Here's a story of another color -- red -- including explosions, isotopes, unpaired electrons, and radioactivity.
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Burning elements is still important in fireworks and also in modern analytical chemistry techniques such as ICP-MS. Also, a fair number of elements are named after their colors: chlorine, rubidium, cesium, chromium, rhodium, indium, iridium, iodine, etc.
The depiction above implies how weakly rubidum holds its outermost electron and why it so readily gives it up to become Rb+. Most anything can pluck it off. Here's a spectacular video of rubidium hitting water:
Naturally occurring rubidium has two isotopes: the stable 85Rb (72.2%) and the radioactive 87Rb (27.8%). 87Rb is considered only "slightly" radioactive--despite its abundance (it is naturally present in seawater)--because of its extremely long half-life of 1010 years. Remember that something has to actually decay in order for it to emit radiation.
37 comments:
chick, what is the reaction equation for the rubidium and water?
@deb: Two steps
First step:
2Rb + 2H2O = 2RbOH + H2 (bubble)
Second step:
2H2 + O2 = 2H20 (boom!)
Net:
2Rb + H2 + O2 = 2RbOH
RbOH is alkaline (a base). That why it's an alkaline metal.
Very cool, thanks :)
With sodium instead of rubidium, you can actually see the steps in the analogous reaction. The chunk of sodium -- no matter its shape -- skitters over the surface of the water, melting into a ball. The ball dissolves, making NaOH and hydrogen gas which may or may not catch fire depending on how fast the hydrogen dissipates.
That would be cool to see on a video.
What interesting to note in the cesium explosion is that it blew out the bottom of the vessel. You can see that the cesium actually sank to the bottom before reacting. This is because cesium is much heavier than water unlike the others.
I saw the container blow out, but did not note it fell to the bottom before the reaction occurred.
I just went back and checked. You see a column of bubbles hit bottom.
I didn't "see" the cesium but I inferred that cesium made them because bubbles rise not fall.
Okay, I see. I was also associating it with the clink of the tongs on the edge of the container lol.
I thought rubidium was that time I lost Marco Rubio inside the palladium night club... it was rubidium ;)
I admire your curiosity, deborah.
@Lem: That joke falls under the rubric of "off-color." ;)
Rubio.. blond.. off-color.. not bad.
I'm still chuckling over Chips Stop Sbottom.
:)
I missed this thread yesterday, somehow!
Interesting information, chickenlittle!
I've been intending to make a periodic table painting using all the derivatives of elements that have been used to make paints through the ages.
It's difficult to winnow the list down. Where does cadmium sulfoselenide belong, for instance?
Where does cadmium sulfoselenide belong, for instance?
You're asking: given a mixture of elements, which one is the chromophore? In that case, I'd say sulfur.
Transition metal ones are easy for the non-chemist and only require you recognize it. Others won't be so easy: red lead vs. white lead?
This sounds like a monograph or book. Has anyone done such an endeavor? "The Chemistry of Pigments"?
Why don't you email me a list of pigments you're stuck on and I'll try and help out. -- maybe save you some time.
Palladian, did you ever see my Pigments Of My Imagination?
"Green is for emeralds. Beryl and emerald are essentially the same material, viz., Be3Al2Si6O18. The only difference is that emerald also contains about 2% chromium, the source of its green color. Chromium also makes rubies red, and sapphires blue..."
How does the same element do that?
How does the same element do that?
Think of the chromium having an upstairs and the energy it takes to get up to the second floor is the photon. The different gems "shape" the electronic house of chromium differently, leading to different energies to reach the second floor.
The technical jargon is contained mathematically in crystal field theory.
"The different gems "shape" the electronic house of chromium differently, leading to different energies to reach the second floor."
Can't quite grasp this. Does different energies mean different amount of photons, or energies other than a photon?
I never quite got color observed vs. color absorbed, etc.
I never thought indigo as a color rang true.
Chromium has electrons. They can move up levels when light impinges, but only to discrete levels -- not part way or half way -- all the way or no way.
I never quite got color observed vs. color absorbed, etc.
Color wheel, complimentarity...take something away and only see what's left.
I never thought indigo as a color rang true.
Tell that to Mr. Roy G. Biv.
I will not. It doesn't even make sense, considering the six-color wheel.
It could be that Mr. Biv was just "buying a vowel" for his mnemonic. Yet its frequency occurs -- frequently. :)
@Deborah: Do you believe that colors can sum? link
If so, than consider starting with white light and subtracting.
Wanna know how nerdy I can be? A couple years ago, I planted three young citrus trees in a row: orange, lemon, and lime. I wanted to remember which was which because to my eye they looked the same. Even the young fruit all start green and only turn orange, yellow, and green as they ripen. I could have made signs, but instead, I planted them O, Y, G.
Total geek :)
Yes, I do/did believe in color sum, as it was taught to me in jr. high.
Is it incorrect, because that's a thought-provoking statement.
Very nice post.
Is it incorrect, because that's a thought-provoking statement.
Sorry, you've lost me.
Very nice post.
Thanks!
I didn't get your meaning when you asked if I believed in the summing of colors, and I could subtract from that.
I did learn in jr. high that white is the combination of all colors, and black is the absence of color.
deborah said...
I will not. It doesn't even make sense, considering the six-color wheel.
I took this to mean that you didn't understand how given white light, if you took out one color it would appear to be its compliment. To illustrate, take that three color thing I linked at 10:38. Start in the middle at white. Take out the blue (move southeast) and you get yellow orange.
Thanks for bearing with all this and for coming back. I do appreciate it. :)
Very cool post, chick. Your blog is one of my favorites. Too bad about Carol Herman, though.
And thanks for the offer of help with the piggyments. I'll compile a list of them (may take a while) and ship it off to you.
I'd love to do that Palladian!
That's neat, I never thought of it that way. Yes, I love these chats also.
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